On February 16, 2007, "Straight Jack", a track featuring Missy Elliott and produced by Polow da Don was leaked.The track entered the Deutsche Black Chart in at #35.In an interview on The Bert Show on the Atlanta radio channel Q100 on February 17, 2004, Thomas claimed that Usher cheated on her: "Usher did the ultimate no-no to me.... Thomas and the rest of the members of TLC were big proponents of encouraging safe sex.
One-third of the iconic girl group TLC told Essence that she isn’t just honing in on dating Black men.
“I want for women — especially for women of color — to not be so closed minded when it comes to love,” the self-identified mixed performer said.
In June 2009, VH1 announced the airing of a reality TV series starring Thomas.
The series, What Chilli Wants, which documents Thomas's quest to find love and manage her life with the help of love and relationship expert Tionna Tee Smalls, premiered on April 11, 2010.
In 2001, she co-starred in the action film Ticker, directed by Albert Pyun and "House Party 3".
She also played a small role in the 1998 film Hav Plenty.Certain tracks that were intended for the album were leaked from 2006 to 2008.A track titled "Gameproof", which featured her TLC bandmate T-Boz, was leaked in spring 2006.The site ended up removing the article and issuing an apology to her son.Rozonda “Chilli” Thomas, 47, wants Black women to shake up their dating habits and explore what it’s like to go out with men outside of their race.It was confirmed that the name of the album would be titled Bi-Polar, but due to scheduling conflicts and constant delays, the album was shelved.